Crystal structures of palladium(II) and copper(II) complexes of meso-phenyl tripyrrinone

被引：31

作者：

Furuta, H ^{[1
]}

Maeda, H

Osuka, A

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Kyoto 6068502, Japan

[2] Kyushu Univ, Grad Sch Engn, Dept Appl Chem, Fukuoka 8128581, Japan

[3] JST, PRESTO, Kawaguchi, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 02期

基金：

日本学术振兴会;

关键词：

N-confused porphyrin; tripyrrin; tripyrrinone; N3O-coordination;

D O I：

10.1016/S1387-7003(02)00712-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Meso-phenyl tripyrrinone (2), which is derived directly from N-confused porphyrin by Cu(II)-assisted oxygenolysis, can serve as a metal coordination ligand using three nitrogens and one oxygen in the core. The crystal structures of Pd(II) and Cu(II) complexes show the similar square-planar N3O-coordination but the mode of oligomeric chains formed in the crystals by pi-pi stacking interaction is different: zig-zag for Cu(II) and straight for Pd(II) complex. (C) 2002 Elsevier Science B.N. All rights reserved.

引用

页码：162 / 164

页数：3

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