New Schiff base zinc(II) complexes exhibiting second harmonic generation

被引：76

作者：

Evans, C ^{[1
]}

Luneau, D ^{[1
]}

机构：

[1] CEA Grenoble, DRFMC, Lab Chim Inorgan & Biol, UMR 5046, F-38054 Grenoble 09, France

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 01期

关键词：

D O I：

10.1039/b104360a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Four bis(salicylaldiminato)zinc(II) complexes have been synthesized from four Schiff bases obtained by the condensation of chiral (R)-(+)-1-phenylethylamine with salicylaldehyde (1), 5-nitrosalicylaldehyde (2), 3,5-dichlorosalicylaldehyde (3) and 5-methoxysalicylaidehyde (4). The complexes crystallize in the noncentrosymmetric space groups P2(1)2(1)2(1) (1), P2(1)(2). and C2 (3, 4). The geometry around the zinc(II) metal center is pseudo-tetrahedral with two oxygen and two nitrogen atoms from the ligands and has the A absolute configuration. Powders of the four compounds exhibit second harmonic generation (SHG) of intensity between that of 3-methyl-4-nitropyridine-1-oxide (POM) and N-(4-nitrophenyl)-(S)-prolinol (NPP).

引用

页码：83 / 86

页数：4