Chiral (S)-(+) 1-substituted aryl-4-(1-phenyl) ethylformamido-5-amino-1,2,3-triazole: A new class of chiral ligands for the silver(I)-promoted enantioselective allylation of aldehydes

被引:6
作者
Chen, MD [1 ]
Zheng, YF
Fan, SX
Gao, GZ
Yang, L
Tian, L
Du, YP
Tang, F
Hua, WY
机构
[1] Nanjing Univ Informat Sci & Technol, Dept Environm Sci & Engn, Nanjing 210044, Peoples R China
[2] China Pharmaceut Univ, Coll Pharm, Nanjing, Peoples R China
基金
中国国家自然科学基金;
关键词
catalytic; chiral ligands; triazole;
D O I
10.1080/00397910500503595
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Some novel chiral ligands, (S)-(+) 1-substituted aryl-4-(1-phenyl) ethylformamido-5-amino-1,2,3-triazoles, were prepared starting from 1-substituted aryl-4-ethoxycarbonyl-5-amino-1,2,3-triazoles and other reagents. They were used as catalytic chiral ligands in the silver (I)-promoted enantioselective allylation reaction of aldehydes with allyltributyltin.
引用
收藏
页码:1063 / 1070
页数:8
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