Chiral bis(oxazolinyl)phenylrhodium(III) complexes as Lewis acid catalysts for enantioselective allylation of aldehydes

被引：103

作者：

Motoyama, Y ^{[1
]}

Narusawa, H ^{[1
]}

Nishiyama, H ^{[1
]}

机构：

[1] Toyohashi Univ Technol, Sch Mat Sci, Aichi 4418580, Japan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 02期

关键词：

D O I：

10.1039/a807716i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of (Phebox)SnMe3 1 [PheboxH = 2,6-bis(oxazolinyl)benzene] and [(c-octene)RhCl](2) in the presence of CCl4 provided air-stable and water-tolerant (Phebox)RhCl2(H2O) complexes 2 which acted as asymmetric catalysts for the enantioselective allylation of aldehydes in up to 80% ee.

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页码：131 / 132

页数：2

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