Preparation and characterization of titanium dioxide thin films by SILAR method

被引:27
作者
Pathan, HM [1 ]
Min, SK [1 ]
Desai, JD [1 ]
Jung, KD [1 ]
Joo, OS [1 ]
机构
[1] Korea Inst Sci & Technol, Econano Res Ctr, Seoul 130650, South Korea
关键词
SILAR; TiO2; synthesis and properties;
D O I
10.1016/j.matchemphys.2005.04.009
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Successive ionic layer adsorption and reaction (SILAR) is a process for depositing uniform, crystalline and conformal thin films by alternating exposures to cations and anions. SILAR has been successfully demonstrated for many metal oxides, but not for titanium dioxide (TiO2). Here we demonstrate process for deposition of TiO2 thin films using SILAR method. Titanium tri-chloride and ammonium hydroxide were used as cationic and anionic sources, respectively. Their surface reactions were found to be complementary and self-limiting, thus providing compact, uniform films with control over thickness of the film. The preparative conditions were optimized to get good-quality TiO2 thin films. The films have been characterized for structural, morphological, compositional, optical and photo-response properties. Growth process, reaction mechanism and annealing effect are also discussed. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:5 / 9
页数:5
相关论文
共 19 条
[1]  
DARLIN KD, 1997, PROGR INORGANIC CHEM, V44
[2]   Structural analysis of TiO2 films grown using microwave-activated chemical bath deposition [J].
Fernández-Lima, F ;
Baptista, DL ;
Zumeta, I ;
Pedrero, E ;
Prioli, R ;
Vigil, E ;
Zawislak, E .
THIN SOLID FILMS, 2002, 419 (1-2) :65-68
[3]   Deposition of titania thin films from aqueous solution by a continuous flow technique [J].
Fuchs, TM ;
Hoffmann, RC ;
Niesen, TP ;
Tew, H ;
Bill, J ;
Aldinger, F .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (05) :1597-1601
[4]   Electrodeposition of TiO2 photocatalyst into porous alumite prepared in phosphoric acid [J].
Ishikawa, Y ;
Matsumoto, Y .
SOLID STATE IONICS, 2002, 151 (1-4) :213-218
[5]  
Justicia I, 2002, ADV MATER, V14, P1399, DOI 10.1002/1521-4095(20021002)14:19<1399::AID-ADMA1399>3.0.CO
[6]  
2-C
[7]   Cathodic electrodeposition of oxide semiconductor thin films and their application to dye-sensitized solar cells [J].
Karuppuchamy, S ;
Nonomura, K ;
Yoshida, T ;
Sugiura, T ;
Minoura, H .
SOLID STATE IONICS, 2002, 151 (1-4) :19-27
[8]   Alternative dielectrics to silicon dioxide for memory and logic devices [J].
Kingon, AI ;
Maria, JP ;
Streiffer, SK .
NATURE, 2000, 406 (6799) :1032-1038
[9]   Atomic layer deposition of transition metals [J].
Lim, BS ;
Rahtu, A ;
Gordon, RG .
NATURE MATERIALS, 2003, 2 (11) :749-754
[10]   Room temperature chemical deposition of amorphous TiO2 thin films from Ti(III) chloride solution [J].
Lokhande, CD ;
Lee, EH ;
Jung, KD ;
Joo, OS .
JOURNAL OF MATERIALS SCIENCE, 2004, 39 (08) :2915-2918