Pendant-arm macrocycles derived from the cyclocondensation reaction of sodium 2,6-diformyl-4-substitutedphenolates and tris-(2-aminoethyl)amine derivatives. Preparation, characterization and properties of their dinuclear copper(II) complexes

被引：8

作者：

Zeng, QD

Gou, SH ^{[1
]}

Fang, JL

Zhu, JJ

You, XZ

机构：

[1] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[3] Nanjing Univ, Analyt Ctr, Nanjing 210093, Peoples R China

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 1999年 / 35卷 / 1-2期

关键词：

pendant-arm macrocycles; dinuclear macrocyclic copper(II) complexes; sodium template; Schiff base cyclocondensation;

D O I：

10.1023/A:1008159301893

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of pendant-arm Schiff base macrocycles have been obtained via the cyclocondensation reaction between sodium 2,6-diformyl-4-substitutedphenolates and tris-(2-aminoethyl)- amine derivatives followed by transmetallation with Cu(ClO4)(2). 6H(2)O. The resulting dinuclear copper(II) complexes have been characterized by elemental analysis, infrared and mass spectra as well as magnetic moments at room temperature. All complexes have been electrochemically investigated, and two typical compounds have been studied with ESR spectra as well.

引用

页码：299 / 309

页数：11

共 24 条

[1] The mononuclear barium and dinuclear copper(II) complexes of a 24-membered bibracchial tetraimine Schiff base macrocycle derived from tris(2-aminoethyl)amine and 2,5-diformylfuran [J].