New ''Cp2Zr''-mediated ring transformations of 2-vinylheterocycles to carbocycles

被引：11

作者：

Hanzawa, Y

Kiyono, H

Tanaka, N

Taguchi, T

机构：

[1] School of Pharmacy, Tokyo Univ. of Pharm. and Life Sci., Hachioji, Tokyo 192-03

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 26期

关键词：

D O I：

10.1016/S0040-4039(97)00989-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Novel ''Cp2Zr''-mediated ring transformations of 2-vinylheterocycles (1, 2) to carbocycles (3, 4, 5) were shown to proceed through an intramolecular allylation of Z-allylic zirconocene species to the epoxide or aziridine intermediate. (C) 1997 Elsevier Science Ltd.

引用

页码：4615 / 4618

页数：4

共 17 条

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