Toward the isolation of functional organic nanotubes

被引:98
作者
Dalgarno, SJ [1 ]
Cave, GWV [1 ]
Atwood, JL [1 ]
机构
[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA
关键词
calixarenes; hydrogen bonds; nanostructures; self-assembly; supramolecular chemistry;
D O I
10.1002/anie.200503035
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) The last straw: Sonication of C-hexylpyrogallol[4]arene with pyrene, acetonitrile, and water results in the formation of crystalline organic nanotubes. Alternating pockets of acetonitrile and water are contained within the large internal diameter of the tube formed by the calixarenes (see picture; the tube and solvent molecules are shown as stick and space-filling representations, respectively). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:570 / 574
页数:5
相关论文
共 28 条
[1]   Toward mimicking viral geometry with metal-organic systems [J].
Atwood, JL ;
Barbour, LJ ;
Dalgarno, SJ ;
Hardie, MJ ;
Raston, CL ;
Webb, HR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (41) :13170-13171
[2]   Organization of the interior of molecular capsules by hydrogen bonding [J].
Atwood, JL ;
Barbour, LJ ;
Jerga, A .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 (08) :4837-4841
[3]   Hydrogen-bonded molecular capsules are stable in polar media [J].
Atwood, JL ;
Barbour, LJ ;
Jerga, A .
CHEMICAL COMMUNICATIONS, 2001, (22) :2376-2377
[4]   Self-recognition, structure, stability, and guest affinity of pyrogallol[4]arene and resorcin[4]arene capsules in solution [J].
Avram, L ;
Cohen, Y .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (37) :11556-11563
[5]   Spontaneous formation of hexameric resorcinarene capsule in chloroform solution as detected by diffusion NMR [J].
Avram, L ;
Cohen, Y .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (51) :15148-15149
[6]   Inner core structure responds to communication between nanocapsule walls [J].
Cave, GWV ;
Antesberger, J ;
Barbour, LJ ;
McKinlay, RM ;
Atwood, JL .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (39) :5263-5266
[7]  
CAVE GWV, 2004, ANGEW CHEM, V116, P5879
[8]  
DALGARNO SJ, UNPUB
[9]  
Dresselhaus M., 1995, SCI FULLERENES CARBO
[10]   Carbohydrate nanotubes [J].
Gattuso, G ;
Menzer, S ;
Nepogodiev, SA ;
Stoddart, JF ;
Williams, DJ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (13-14) :1451-1454