Molecular recognition: The demonstration of 1,3-bis[(pyrid-2-ylamino)carbonyl]adamantane as an exceptionally versatile assembler of one-dimensional motifs

被引：66

作者：

Karle, IL ^{[1
]}

Ranganathan, D ^{[1
]}

Haridas, V ^{[1
]}

机构：

[1] CSIR,REG RES LAB,BIOMOL RES UNIT,TRIVANDRUM 695019,KERALA,INDIA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1997年 / 119卷 / 12期

关键词：

D O I：

10.1021/ja9623121

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Syntheses and crystal structures of 1,3-bis[(pyrid-2-ylamino)carbonyl]adamantane (1) and its perchlorate salt, copper(II) complex, and 1:1 complexes with a large variety of simple and functionalized 1,omega-alkanedicarboxylic acids, HOOC-X-COOH [X=(CH2)(n), n=2, 3, 5, and 8; -CH2-CO (alpha-ketoglutaric acid); CH=CH (maleic acid)] are described. The molecule 1 exhibits remarkable adaptability with respect to the conformation of its two hydrogen-bonding subunits to suit the requirements of the assembling partners so as to generate persistently one-dimensional motifs, for example, infinite zig-zag ribbons with perchlorate ions and chains with both Cu(II) ions and dicarboxylic acids.

引用

页码：2777 / 2783

页数：7

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