Alternating copolymerization of carbon monoxide and olefins by single-site metal catalysis

被引:293
作者
Bianchini, C [1 ]
Meli, A [1 ]
机构
[1] CNR, Ist Studio Stereochim & Energet Composti Coor, I-50132 Florence, Italy
关键词
alternating copolymerization; polyketones; carbon monoxide; alkene; asymmetric; stereoselective;
D O I
10.1016/S0010-8545(01)00405-2
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The alternating copolymerization of carbon monoxide and olefins is a reaction that transition metal complexes, generally containing palladium, catalyze in different phase variation systems. The polyketone products are not only low cost thermal plastics that can be made but also polymeric materials featured by unique chemical and physical properties. These properties can be finely tuned by an appropriate choice of the catalyst and olefinic comonomer. After introducing the topic, the specific metal catalysts for each type of olefinic substrate are described together with the reaction mechanisms involved. (C) 2002 Elsevier Science B.N. All rights reserved.
引用
收藏
页码:35 / 66
页数:32
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