Growth kinetics and crystal structure of semiconductor nanowires

被引:282
作者
Dubrovskii, V. G. [1 ,2 ]
Sibirev, N. V. [1 ]
Harmand, J. C. [3 ]
Glas, F. [3 ]
机构
[1] Russian Acad Sci, St Petersburg Phys & Technol Ctr Res & Educ, St Petersburg 195220, Russia
[2] Russian Acad Sci, AF Ioffe Phys Tech Inst, St Petersburg 194021, Russia
[3] CNRS LPN, F-91460 Marcoussis, France
关键词
crystal structure; elemental semiconductors; gallium arsenide; III-V semiconductors; nanotechnology; nanowires; semiconductor growth; semiconductor quantum wires; silicon; solid-state phase transformations;
D O I
10.1103/PhysRevB.78.235301
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Theoretical model for the growth of semiconductor nanowires is developed, which enables one to determine the growth conditions under which the formation of nanowires is possible. General expression for the nanowire growth rate as function of its radius and the growth conditions is obtained and analyzed. The model also describes the transformation from cubic to hexagonal crystal phase of nanowires. It is shown that the observed crystal structure is controlled mainly by the growth kinetics. Structural diagrams and probabilities of cubic and hexagonal phase formation are calculated as functions of supersaturation and nanowire radius within the plausible range of material parameters. Numerical estimates for the domains of phase mixing and phase purity are presented and analyzed.
引用
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页数:10
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