Fullerenes by pyrolysis of hydrocarbons and synthesis of isomeric methanofullerenes

被引：56

作者：

Osterodt, J ^{[1
]}

Zett, A ^{[1
]}

Vogtle, F ^{[1
]}

机构：

[1] UNIV BONN,INST ORGAN CHEM & BIOCHEM,D-53121 BONN,GERMANY

来源：

TETRAHEDRON | 1996年 / 52卷 / 14期

关键词：

D O I：

10.1016/0040-4020(96)00103-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In part A the pyrolysis of various hydrocarbons, cyclopentadienide metal complexes, and mellitic acid anhydride leading to fullerenes is introduced. Possible mechanisms are discussed on the background of the structures of the educt molecules. In part B the synthesis of some new 'crowned methanofullerenes' in a new one-step reaction is described. The influence of the substituents on the separation of the resulting isomers is investigated. Calculations were made to obtain information about the formation and isomerisation of these isomers. (C) 1996 Elsevier Science Ltd

引用

页码：4949 / 4962

页数：14

共 66 条

[1] FULLERENES AND THEIR IONS IN HYDROCARBON FLAMES [J].

AHRENS, J ;

BACHMANN, M ;

BAUM, T ;

GRIESHEIMER, J ;

KOVACS, R ;

WEILMUNSTER, P ;

HOMANN, KH .

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1994, 138 :133-148

[2] METHANOFULLERENES AND METHANOFULLEROIDS HAVE DIFFERENT ELECTROCHEMICAL-BEHAVIOR AT NEGATIVE POTENTIALS [J].

ARIAS, F ;

ECHEGOYEN, L ;

WILSON, SR ;

LU, Q ;

LU, QY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (04) :1422-1427

[3] THE FORMATION OF C-60 AND ITS PRECURSORS IN NAPHTHALENE FLAMES [J].

BACHMANN, M ;

GRIESHEIMER, J ;

HOMANN, KH .

CHEMICAL PHYSICS LETTERS, 1994, 223 (5-6) :506-510

[4] AZIRIDINO[2',3'/1,6][60]FULLERENE - ISOLATION OF THE FIRST CLOSED [5,6]-BRIDGED FULLERENE ADDUCT [J].

BANKS, MR ;

CADOGAN, JIG ;

GOSNEY, I ;

HODGSON, PKG ;

LANGRIDGESMITH, PRR ;

MILLAR, JRA ;

PARKINSON, JA ;

RANKIN, DWH ;

TAYLOR, AT .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (08) :887-888

[5] FULLERENE IONS AND THEIR RELATION TO PAH AND SOOT IN LOW-PRESSURE HYDROCARBON FLAMES [J].

BAUM, T ;

LOFFLER, S ;

LOFFLER, P ;

WEILMUNSTER, P ;

HOMANN, KH .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1992, 96 (07) :841-857

[6]

BELZ T, 1994, ANGEW CHEM INT EDIT, V33, P1866, DOI 10.1002/anie.199418661

[7]

BELZ T, 1994, ANGEW CHEM, V106, P1919

[8] GAS-PHASE ION CHROMATOGRAPHY - TRANSITION-METAL STATE SELECTION AND CARBON CLUSTER FORMATION [J].

BOWERS, MT ;

KEMPER, PR ;

VON HELDEN, G ;

VANKOPPEN, PAM .

SCIENCE, 1993, 260 (5113) :1446-1451

[9] EXPERIMENTAL STUDIES ON THE FORMATION PROCESS OF C-60 [J].

BROYER, M ;

GOERES, A ;

PELLARIN, M ;

SEDLMAYR, E ;

VIALLE, JL ;

WOSTE, L .

CHEMICAL PHYSICS LETTERS, 1992, 198 (1-2) :128-134

[10] FULLERENE FORMATION IN SPUTTERING AND ELECTRON-BEAM EVAPORATION PROCESSES [J].

BUNSHAH, RF ;

JOU, SK ;

PRAKASH, S ;

DOERR, HJ ;

ISAACS, L ;

WEHRSIG, A ;

YERETZIAN, C ;

CYNN, HC ;

DIEDERICH, F .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (17) :6866-6869

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