Fullerenes by pyrolysis of hydrocarbons and synthesis of isomeric methanofullerenes

被引：56

作者：

Osterodt, J ^{[1
]}

Zett, A ^{[1
]}

Vogtle, F ^{[1
]}

机构：

[1] UNIV BONN,INST ORGAN CHEM & BIOCHEM,D-53121 BONN,GERMANY

来源：

TETRAHEDRON | 1996年 / 52卷 / 14期

关键词：

D O I：

10.1016/0040-4020(96)00103-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In part A the pyrolysis of various hydrocarbons, cyclopentadienide metal complexes, and mellitic acid anhydride leading to fullerenes is introduced. Possible mechanisms are discussed on the background of the structures of the educt molecules. In part B the synthesis of some new 'crowned methanofullerenes' in a new one-step reaction is described. The influence of the substituents on the separation of the resulting isomers is investigated. Calculations were made to obtain information about the formation and isomerisation of these isomers. (C) 1996 Elsevier Science Ltd

引用

页码：4949 / 4962

页数：14

共 66 条

[31] FULLERENES C60 AND C70 IN FLAMES [J].

HOWARD, JB ;

MCKINNON, JT ;

MAKAROVSKY, Y ;

LAFLEUR, AL ;

JOHNSON, ME .

NATURE, 1991, 352 (6331) :139-141

[32] PREPARATION AND CHARACTERIZATION OF FULLEROID AND METHANOFULLERENE DERIVATIVES [J].

HUMMELEN, JC ;

KNIGHT, BW ;

LEPEQ, F ;

WUDL, F ;

YAO, J ;

WILKINS, CL .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (03) :532-538

[33] ANNEALING C-60+ - SYNTHESIS OF FULLERENES AND LARGE CARBON RINGS [J].

HUNTER, J ;

FYE, J ;

JARROLD, MF .

SCIENCE, 1993, 260 (5109) :784-786

[34] IMPROVED PURIFICATION OF C-60 AND FORMATION OF SIGMA-HOMOAROMATIC AND PI-HOMOAROMATIC METHANO-BRIDGED FULLERENES BY REACTION WITH ALKYL DIAZOACETATES [J].

ISAACS, L ;

WEHRSIG, A ;

DIEDERICH, F .

HELVETICA CHIMICA ACTA, 1993, 76 (03) :1231-1250

[35] PHOTOCHEMICAL FULLEROID TO METHANOFULLERENE CONVERSION VIA THE DI-PI-METHANE (ZIMMERMAN) REARRANGEMENT [J].

JANSSEN, RAJ ;

HUMMELEN, JC ;

WUDL, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (01) :544-545

[36] THE FORMATION OF QUASI-ICOSAHEDRAL SPIRAL SHELL CARBON PARTICLES [J].

KROTO, HW ;

MCKAY, K .

NATURE, 1988, 331 (6154) :328-331

[37] C-60 - BUCKMINSTERFULLERENE [J].

KROTO, HW ;

HEATH, JR ;

OBRIEN, SC ;

CURL, RF ;

SMALLEY, RE .

NATURE, 1985, 318 (6042) :162-163

[38] HETEROCUMULENES .7. MATRIX SPECTROSCOPIC ANALYSIS FOR EXISTENCE OF C7O2 (1,2,3,4,5,6-HEPTAHEXAENE-1,7-DIONE) [J].

MAIER, G ;

REISENAUER, HP ;

ULRICH, A .

TETRAHEDRON LETTERS, 1991, 32 (35) :4469-4472

[39] COMBUSTION SYNTHESIS OF FULLERENES [J].

MCKINNON, JT ;

BELL, WL ;

BARKLEY, RM .

COMBUSTION AND FLAME, 1992, 88 (01) :102-112

[40] FIRST X-RAY DETERMINATION OF CYCLOPROPANE STRUCTURE IN METHANOFULLERENES [J].

OSTERODT, J ;

NIEGER, M ;

VOGTLE, F .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (13) :1607-1608

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