Atropo-enantioselective synthesis of an axially chiral C1-symmetric phosphine ligand and its application in the asymmetric hydrosilylation of styrenes

被引：32

作者：

Bringmann, G

Wuzik, A

Breuning, M

Henschel, P

Peters, K

Peters, EM

机构：

[1] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany

[2] Max Planck Inst Festkorperforsch, D-70506 Stuttgart, Germany

来源：

TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 15期

关键词：

D O I：

10.1016/S0957-4166(99)00299-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The axially chiral monodentate phosphine P-8 was synthesized in enantiomerically pure form, starting from the readily available, configurationally unstable lactone 1. Furthermore, its application as a ligand in the Pd-catalyzed stereoselective hydrosilylation of styrenes was investigated. (C) 1999 Elsevier Science Ltd. All rights reserved.

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页码：3025 / 3031

页数：7

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