Synthesis, isolation and characterization of cationic gold(I) N-heterocyclic carbene (NHC) complexes

被引：101

作者：

de Frémont, P

Stevens, ED

Fructos, MR

Díaz-Requejo, MM

Pérez, PJ

Nolan, SP ^{[1
]}

机构：

[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

[2] Univ Huelva, CSIC, Unidad Asoc,Dept Quim & Ciencia Mat, Lab Catalisis Homogenea, Huelva 21007, Spain

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 19期

关键词：

D O I：

10.1039/b601547f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A number of cationic gold(I) complexes have been synthesized and found to be stabilized by the use of N-heterocyclic carbene ligands. These species are often employed as in situ-generated reactive intermediates in gold catalyzed organic transformations. An isolated, well-defined species was tested in gold-mediated carbene transfer reactions from ethyl diazoacetate.

引用

页码：2045 / 2047

页数：3

共 36 条

[1] FORMATION OF GOLD(I) HALIDE AND THIOCYANATE COMPLEXES IN PYRIDINE AND ACETONITRILE AND THE STRUCTURES OF GOLD(I) SOLVATES IN THESE SOLVENTS - A THERMODYNAMIC AND EXAFS SPECTROSCOPIC STUDY
AHRLAND, S
NILSSON, K
PERSSON, I
YUCHI, A
PENNERHAHN, JE
[J]. INORGANIC CHEMISTRY, 1989, 28 (10) : 1833 - 1838
[2] A STABLE CRYSTALLINE CARBENE
ARDUENGO, AJ
HARLOW, RL
KLINE, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) : 361 - 363
[3] Synthetic, structural and spectroscopic studies of (pseudo)halo(1,3-di-tert-butylimidazol-2-ylidine) gold complexes
Baker, MV
Barnard, PJ
Brayshaw, SK
Hickey, JL
Skelton, BW
White, AH
[J]. DALTON TRANSACTIONS, 2005, (01) : 37 - 43
[4] Catalytic transformations of diazo compounds promoted by platinum(0) and dicationic platinum(II) complexes
Bertani, R
Biasiolo, M
Darini, K
Michelin, RA
Mozzon, M
Visentin, F
Zanotto, L
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 642 (1-2) : 32 - 39
[5] Catalytic activity of dicationic platinum(II) and rhodium(II) complexes towards 9-diazofluorene
Bertani, R
Michelin, RA
Mozzon, M
Sassi, A
Basato, M
Biffis, A
Martinati, G
Zecca, M
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2001, 4 (06) : 281 - 284
[6] REACTIONS OF C-IMIDAZOLYLLITHIUM DERIVATIVES WITH GROUP-IB COMPOUNDS - TRIS[MU-(1-ALKYLIMIDAZOLATO-N3,C2)]TRI-GOLD(I) AND TRI-SILVER(I) - CRYSTAL-STRUCTURE OF BIS(1-BENZYLIMIDAZOLIN-2-YLIDEN)GOLD(I) CHLORIDE
BONATI, F
BURINI, A
PIETRONI, BR
BOVIO, B
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 375 (01) : 147 - 160
[7] Second generation N-heterocyclic carbene-Pt(0) complexes as efficient catalysts for the hydrosilylation of alkenes
Buisine, O
Berthon-Gelloz, G
Brière, JF
Stérin, S
Mignani, G
Branlard, P
Tinant, B
Declercq, JP
Markó, IE
[J]. CHEMICAL COMMUNICATIONS, 2005, (30) : 3856 - 3858
[8] CONZELMANN W, 1982, Z ANORG ALLG CHEM, V485, P81
[9] CRYSTAL STRUCTURE OF PHENYLETHYNYL(ISOPROPYLAMINE)GOLD(I)
CORFIELD, PW
SHEARER, HMM
[J]. ACTA CRYSTALLOGRAPHICA, 1967, 23 : 156 - &
[10] Synthesis and structural characterization of N-heterocyclic carbene gold(I) complexes
de Frémont, P
Scott, NM
Stevens, ED
Nolan, SP
[J]. ORGANOMETALLICS, 2005, 24 (10) : 2411 - 2418

← 1 2 3 4 →