Bidirectional transfer of phenyl and methyl groups between PtIV and boron in platinum dipyridylborato complexes

被引：40

作者：

Khaskin, Eugene ^{[1
]}

Zavalij, Peter Y. ^{[1
]}

Vedernikov, Andrei N. ^{[1
]}

机构：

[1] Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 31期

关键词：

D O I：

10.1021/ja804222c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of weakly Lewis basic DMSO methyl group migration between B and Pt-IV in dipyridylborate trihydrocarbyl Pt-IV complexes is reversible; the preferred direction of Ph group migration in THF solution is from Pt-IV to B.

引用

页码：10088 / +

页数：3

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