Fluorination of nonactivated haloarenes via arynes under mild conditions, resulting from further studies toward Ar-F reductive elimination from palladium(H)

被引：62

作者：

Grushin, Vladimir V. ^{[1
]}

Marshall, William J. ^{[1
]}

机构：

[1] EI DuPont Nemours & Co Inc, Cent Res & Dev, Expt Stn, Wilmington, DE 19880 USA

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 19期

关键词：

D O I：

10.1021/om800520e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Attempted preparation of NN- and S,S-chelate-stabilized arylpalladium fluorides has led to the finding of aryne-mediated fluorination of nonactivated haloarenes with Me4NF in DMSO under mild conditions.

引用

页码：4825 / 4828

页数：4

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