Reaction of alkoxyphenols and alkynoates in the presence of a catalytic amount of Pd(OAc)(2) in trifluoroacetic acid at room temperature gave coumarin derivatives in high yields. This procedure provides a convenient method for direct synthesis of coumarin derivatives under very mild conditions.
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Hepworth J.D., 1984, COMPREHENSIVE HETERO, V3, P737, DOI DOI 10.1016/B978-008096519-2.00046-1