Bulk heterojunction organic photovoltaic cell fabricated with a p-type conjugated star-shaped molecule

被引:13
作者
Lee, Tae Wan [2 ]
Kim, Dae Cheol [2 ]
Kang, Nam Su [1 ]
Yu, Jae Woong [1 ]
Cho, Min Ju [2 ]
Kim, Kyung Hwan [2 ]
Choi, Dong Hoon [2 ]
机构
[1] Korea Inst Sci & Technol, Ctr Energy Mat Res, Seoul 136791, South Korea
[2] Korea Univ, Dept Chem, Adv Mat Chem Res Ctr, Seoul 136701, South Korea
关键词
D O I
10.1246/cl.2008.866
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new multibranched crystalline Molecule was synthesized through Horner-Emmons reactions Using hexyl-substituted thiophene-based carbaldehydes as dendrons and benzene-1,2,4,5-tetramethylphosphonic acid octaethyl ester its the core unit. The molecule was employed to fabricate organic photovoltaic (OPV) cells with methanofullerene [6.6]-phenyl C61-butyric acid methyl ester (PCBM). Poly(3-hexylthiophene) (P3HT) wits also used its a dopant to improve the film quality and power conversion efficiency. As a result, the short-circuit current density and open Circuit voltage were increased when P3HT was added into 4(HPBT) and PCBM dyad. resulting in a hi,,her power conversion efficiency of around 0.6%.
引用
收藏
页码:866 / 867
页数:2
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