Solution structure, dynamics and speciation of perfluoroaryl boranes through 1H, 11B and 19F NMR spectroscopy

被引：88

作者：

Beringhelli, Tiziana ^{[1
]}

Donghi, Daniela ^{[1
]}

Maggioni, Daniela ^{[1
]}

D'Alfonso, Giuseppe ^{[1
]}

机构：

[1] Univ Milan, Dipartimento Chim Inorgan Metallorgan & Analit, I-20133 Milan, Italy

来源：

COORDINATION CHEMISTRY REVIEWS | 2008年 / 252卷 / 21-22期

关键词：

Perfluoroaryl boranes; NMR spectroscopy; Lewis acids; Hydrogen bonds; Dynamical behaviour;

D O I：

10.1016/j.ccr.2008.01.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Multinuclear NMR spectroscopy has been used to study the solution properties of several perfluoroaryl borane derivatives. The information obtained from all the NMR active isotopes present in these molecules made it possible to establish not only chemical identity, structure and dynamics of their reaction products, but also the complexity of the solution speciation. In other words, multinuclear NMR helped in unravelling the real forms in which they are present in solution, that in some cases can change dramatically according to even slight changes of the solution conditions. Examples will be presented related to the chemistry of tris(pentafluorophenyl)borane, B(C6F5)(3), and bis(pentafluorophenyl)borinic acid, B(C6F5)(2)OH. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：2292 / 2313

页数：22

共 115 条

[61] INVESTIGATION OF EXCHANGE PROCESSES BY 2-DIMENSIONAL NMR-SPECTROSCOPY [J].

JEENER, J ;

MEIER, BH ;

BACHMANN, P ;

ERNST, RR .

JOURNAL OF CHEMICAL PHYSICS, 1979, 71 (11) :4546-4553

[62] Pentafluoroaryl transfer from tris(pentafluorophenyl)boron hydrate to nickel.: Synthesis and X-ray crystal structure of (PPh2CH2C(O)Ph)Ni(C6F5)2 [J].

Kalamarides, HA ;

Iyer, S ;

Lipian, J ;

Rhodes, LF ;

Day, C .

ORGANOMETALLICS, 2000, 19 (19) :3983-3990

[63]

Kaplan J. I., 1980, NMR CHEM EXCHANGING

[64]

Kehr G, 2001, EUR J INORG CHEM, P535

[65]

Kehr G, 2000, CHEM-EUR J, V6, P258, DOI 10.1002/(SICI)1521-3765(20000117)6:2<258::AID-CHEM258>3.3.CO

[66]

2-5

[67]

KIDD RG, 1983, NMR NEWLY ACCESSIBLE, V2

[68] Homogeneous transition metal catalysis: from the water gas shift reaction to nuclear waste vitrification [J].

King, RB .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 586 (01) :2-17

[69] Ketone coordination chemistry of the diborane t-BuCH=C[B(C6F5)2]2 [J].

Köhler, K ;

Piers, WE .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1998, 76 (09) :1249-1255

[70]

KRATZER R, 2001, Patent No. 19962814

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