Explaining the emergence of cooperative phenomena

被引:31
作者
Liu, C [1 ]
机构
[1] Univ Florida, Dept Philosophy, Gainesville, FL 32611 USA
关键词
D O I
10.1086/392718
中图分类号
N09 [自然科学史]; B [哲学、宗教];
学科分类号
01 ; 0101 ; 010108 ; 060207 ; 060305 ; 0712 ;
摘要
Phase transitions are well-understood phenomena in thermodynamics (TD), but it turns out that they are mathematically impossible in finite SM systems. Hence, phase transitions are truly emergent properties. They appear again at the thermodynamic limit (TL), i.e., in infinite systems. However, most, if not all, systems in which they occur are finite, so whence comes the justification for taking TL? The problem is then traced back to the TD characterization of phase transitions, and it turns out that the characterization is the result of serious idealizations which under suitable circumstances approximate actual conditions.
引用
收藏
页码:S92 / S106
页数:15
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