Levels and distribution of organochlorine pesticides, polychlorinated biphenyls and polybrominated diphenyl ethers in sediments and biota from the Danube Delta, Romania

被引:163
作者
Covaci, A
Gheorghe, A
Hulea, O
Schepens, P
机构
[1] Univ Instelling Antwerp, Toxicol Ctr, B-2610 Antwerp, Belgium
[2] Univ Bucharest, Fac Chem, Dept Analyt Chem, Bucharest 050663, Romania
[3] Romanian Ornithol Soc, Bucharest 011466, Romania
关键词
Danube Delta; sediment; fish; cormorant; polychlorinated biphenyls; organochlorine pesticides; polybrominated diphenyl ethers;
D O I
10.1016/j.envpol.2005.06.008
中图分类号
X [环境科学、安全科学];
学科分类号
08 [工学]; 0830 [环境科学与工程];
摘要
Concentrations of polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs) and organochlorine pesticides (OCPs), such as dichlorodiphenyltrichloroethane (DDT) and analogues, (HCHs) and hexachlorobenzene (HCB). were measured in sediments and biota (invertebrates. 11 fish species and cormorant tissues) collected in 2001 from the Danube Delta, the biggest European wetland. DDTs were the predominant pollutants in all samples, A high variability in the concentrations or pollutants within the same species was observed and this was related to sampling location. age. length and sex. DDTs were also the main organohalogenated contaminants in cormorant muscle and liver. followed by PCBs. HCHs. HCB and PBDEs. The present levels of DDTs in cormorant tissues are lower than levels Measured ill cormorant eggs sampled from the Danube Delta in 1982 and 1997, respectively. The variance of delta(15)N for herbivores was much greater than for carnivores, while carp and bream showed higher delta(15)N signatures than expected. probably due to a higher dietary typically more delta(15)N enriched relative to pelagic biota. (C) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:136 / 149
页数:14
相关论文
共 53 条
[1]
Organochlorine contamination in bird's eggs from the Danube Delta [J].
Aurigi, S ;
Focardi, S ;
Hulea, D ;
Renzoni, A .
ENVIRONMENTAL POLLUTION, 2000, 109 (01) :61-67
[2]
DDT is still a problem in developed countries: the heavy pollution of Lake Maggiore [J].
Binelli, A ;
Provini, A .
CHEMOSPHERE, 2003, 52 (04) :717-723
[3]
Bratanova Z, 1998, FRESEN ENVIRON BULL, V7, P495
[4]
Towards a global historical emission inventory for selected PCB congeners - a mass balance approach 1. Global production and consumption [J].
Breivik, K ;
Sweetman, A ;
Pacyna, JM ;
Jones, KC .
SCIENCE OF THE TOTAL ENVIRONMENT, 2002, 290 (1-3) :181-198
[5]
Biomagnification of polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs) studied in pike (Esox lucius), perch (Perca fluviatilis) and roach (Rutilus rutilus) from the Baltic Sea [J].
Burreau, S ;
Zebühr, Y ;
Broman, D ;
Ishaq, R .
CHEMOSPHERE, 2004, 55 (07) :1043-1052
[6]
Tissue distribution of 2,2′,4,4′-tetrabromo[14C]diphenyl ether ([14C]-PBDE 47) in pike (Esox lucius) after dietary exposure -: a time series study using whole body autoradiography [J].
Burreau, S ;
Broman, D ;
Örn, U .
CHEMOSPHERE, 2000, 40 (9-11) :977-985
[7]
Optimized separation and determination of methyl sulfone metabolites of polychlorinated biphenyls (PCBs) and p,p′-DDE in biota samples [J].
Chu, SG ;
Covaci, A ;
Haraguchi, K ;
Schepens, P .
ANALYST, 2002, 127 (12) :1621-1626
[8]
Polybrominated diphenyl ethers, polychlorinated biphenyls and organochlorine pesticides in sediment cores from the Western Scheldt river (Belgium): analytical aspects and depth profiles [J].
Covaci, A ;
Gheorghe, A ;
Voorspoels, S ;
Maervoet, J ;
Steen Redeker, E ;
Blust, R ;
Schepens, P .
ENVIRONMENT INTERNATIONAL, 2005, 31 (03) :367-375
[9]
Selected persistent organochlorine pollutants in Romania [J].
Covaci, A ;
Hura, C ;
Schepens, P .
SCIENCE OF THE TOTAL ENVIRONMENT, 2001, 280 (1-3) :143-152
[10]
Marine mammals from Northeast Atlantic:: relationship between their trophic status as determined by δ13C and δ15N measurements and their trace metal concentrations [J].
Das, K ;
Beans, C ;
Holsbeek, L ;
Mauger, G ;
Berrow, SD ;
Rogan, E ;
Bouquegneau, JM .
MARINE ENVIRONMENTAL RESEARCH, 2003, 56 (03) :349-365