Synthesis and characterization of a three-dimensional open-framework lead(II) carboxyethylphosphonate, Pb3(O2CCH2CH2PO3)2

被引：106

作者：

Ayyappan, S ^{[1
]}

de Delgado, GD

Cheetham, AK

Férey, G

Rao, CNR

机构：

[1] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

[2] Univ Versailles St Quentin En Yvelines, F-78035 Versailles, France

[3] Jawaharlal Nehru Ctr Adv Sci Res, Bangalore 560064, Karnataka, India

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 17期

关键词：

D O I：

10.1039/a905326c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal synthesis and single crystal XRD characterization of a three-dimensional open-framework lead(II) carboxyethylphosphonate, Pb-3(O2CCH2CH2PO3)(2), is described; the structure contains PbO3, PbO4 and PbO5 polyhedra, each with stereochemically active lone pairs of electrons, and exhibits several types of channels.

引用

页码：2905 / +

页数：4

共 21 条

[1] Synthesis and structural characterization of a novel tin(II) phosphonate, Sn2(O3PCH3)(C2O4) [J].

Adair, B ;

Natarajan, S ;

Cheetham, AK .

JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (06) :1477-1479

[2] SYNTHESIS OF LAYERED ZR(O3PCH2CH2COCL)2 FROM ZR(O3PCH2CH2COOH)2 [J].

BURWELL, DA ;

THOMPSON, ME .

CHEMISTRY OF MATERIALS, 1991, 3 (01) :14-17

[3]

CLEARFIELD A, 1996, CURR OPIN SOLID ST M, V1, P266

[4] Nonhydrolytic sol-gel routes to layered metal(IV) and silicon phosphonates [J].

Corriu, RJP ;

Leclercq, D ;

Mutin, PH ;

Sarlin, L ;

Vioux, A .

JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (08) :1827-1833

[5] Synthesis and characterization of Co3(O2CCH2CH2PO3)2•6H2O, a metal carboxylate-phosphonate with a framework structure [J].

Distler, A ;

Sevov, SC .

CHEMICAL COMMUNICATIONS, 1998, (09) :959-960

[6] SYNTHESIS, STRUCTURE, AND REACTIVITY OF SOME FUNCTIONALIZED ZINC AND COPPER(II) PHOSPHONATES [J].

DRUMEL, S ;

JANVIER, P ;

BARBOUX, P ;

BUJOLIDOEUFF, M ;

BUJOLI, B .

INORGANIC CHEMISTRY, 1995, 34 (01) :148-156

[7] 71Ga and 31P solid state NMR:: a powerful tool for the characterization of the first gallium phosphonates [J].

Fredoueil, F ;

Massiot, D ;

Poojary, D ;

Bujoli-Doeuff, M ;

Clearfield, A ;

Bujoli, B .

CHEMICAL COMMUNICATIONS, 1998, (02) :175-176

[8] Intercalation of alkanediols into layered vanadyl phenyl and ethylphosphonate [J].

Gendraud, P ;

Bigey, L ;

Gueho, C ;

deRoy, ME ;

Besse, JP .

CHEMISTRY OF MATERIALS, 1997, 9 (02) :539-545

[9] Synthesis of layered nickel phosphonate materials based on a topotactic approach [J].

Hix, GB ;

Harris, KDM .

JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (03) :579-584

[10] ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM [J].

KRESGE, CT ;

LEONOWICZ, ME ;

ROTH, WJ ;

VARTULI, JC ;

BECK, JS .

NATURE, 1992, 359 (6397) :710-712

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