Synthesis, Structure, Chromatic Properties, and Induced Circular Dichromism of Polydiacetylenes with an Extended Conjugated System in the Side Chain

被引：8

作者：

Dei, Satoshi ^{[1
]}

Matsumoto, Akikazu ^{[1
]}

机构：

[1] Osaka City Univ, Grad Sch Engn, Dept Appl Chem, Sumiyoshi Ku, Osaka 5588585, Japan

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2009年 / 210卷 / 01期

关键词：

CD spectrum; chiral polymer; conjugating polymer; radical polymerization; solid-state polymerization; solvatochromism; UV-vis absorption; SOLID-STATE POLYMERIZATION; ORGANIC INTERCALATION SYSTEM; HYDROGEN-BOND NETWORKS; TOPOCHEMICAL POLYMERIZATION; STEREOREGULAR POLY((4-CARBOXYPHENYL)ACETYLENE); MACROMOLECULAR STEREOCHEMISTRY; CHIRALITY ASSIGNMENT; HELICAL POLYMERS; GUEST MOLECULES; THERMOCHROMISM;

D O I：

10.1002/macp.200800488

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We synthesized PDAs with a 4-carboxyphenyl substituent directly connected to the conjugating main chain in order to investigate the effects of the side chain structure on the chromatic properties of the polymers. A series of 1,3-alkadiynyl-4-benzoic acids (m,Ph-DA-CO2H) and their 1-naphthylmethylammonium salts (m,Ph-DA-Naph) were under UV and gamma-ray irradiation. The resulting poly(m,Ph-DA-CO2H)s had absorption bands in their UV-vis spectra in a wavelength region longer than those for the poly(m,Ph-DA-Naph)s and the other PDAs. We report the first example of the induced circular dichromism of poly(m,Ph-DA-CO2H) in the combination with a chiral (1-cyclohexyl)ethylamine in the dispersion and in the solid state by an acid/base interaction. prepared and polymerized

引用

页码：11 / 21

页数：11

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