Comparison of Chiral and Racemic Forms of Zinc Cyclohexane trans-1,2-Dicarboxylate Frameworks: A Structural, Computational, and Calorimetric Study

被引：37

作者：

Bailey, Andrew J. ^{[2
]}

Lee, Clare ^{[4
]}

Feller, Russell K. ^{[3
]}

Orton, James B. ^{[1
]}

Mellot-Draznieks, Caroline ^{[5
]}

Slater, Ben ^{[5
]}

Harrison, William T. A. ^{[4
]}

Simoncic, P. ^{[3
]}

Navrotsky, A. ^{[6
]}

Grossel, Martin C. ^{[2
]}

Cheetham, Anthony K. ^{[1
]}

机构：

[1] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England

[2] Univ Southampton, Sch Chem, Southampton SO9 5NH, Hants, England

[3] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

[4] Univ Aberdeen, Dept Chem, Aberdeen AB9 1FX, Scotland

[5] UCL, Dept Chem, London WC1E 6BT, England

[6] Univ Calif Davis, Peter A Rock Thermochem Lab, Davis, CA 95616 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 45期

基金：

美国国家科学基金会; 英国工程与自然科学研究理事会;

关键词：

calorimetry; chirality; crystal engineering; molecular modeling; organic-inorganic hybrid composites;

D O I：

10.1002/anie.200802564

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) An integrated study of the organic-inorganic framework material zinc cyclohexane trans-1,2-dicarboxylate involving synthesis,structure elucidation, computer simulation,and calorimetry shows that the chiral R,R form (right in picture) is less stable than its racemic R,R/S,S analogue (left) and adopts a layered structure with a fundamentally different topology. The results point to the possibility that the structural diversity of racemic frameworks and their homochiral analogues may be much greater than has hitherto been suspected. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8634 / 8637

页数：4

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