A pH- and temperature-phased two-stage process for hydrogen and methane production from food waste

被引:248
作者
Chu, Chun-Feng [1 ]
Li, Yu-You [2 ]
Xu, Kai-Qin [3 ,4 ]
Ebie, Yoshitaka [3 ]
Inamori, Yuhei [5 ]
Kong, Hai-Nan [1 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Environm Sci & Engn, Shanghai 200240, Peoples R China
[2] Tohoku Univ, Dept Civil & Environm Engn, Sendai, Miyagi 9808579, Japan
[3] Natl Inst Environm Studies, Tsukuba, Ibaraki 3058506, Japan
[4] Wuhan Univ, State Key Lab Water Resources & Hydropower Engn S, Wuhan 430072, Peoples R China
[5] Fukushima Univ, Fac Symbiot Syst Sci, Fukushima 9601296, Japan
关键词
Bio-hydrogen; Food waste; Mesophilic methanogenesis; Thermophilic hydrogenesis; pH-phased two-Stage process;
D O I
10.1016/j.ijhydene.2008.06.060
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A pH-phased two-stage fermentation process combined thermophilic hydrogen production and mesophilic methane production with recirculation of the digested sludge was suggested in this study and its treatment performance was demonstrated by a continuous experiment treating organic fraction of municipal solid wastes (OFMSW). A thermophilic hydrogen production reactor was operated at a hydraulic retention time (HRT) of 1.3 days, corresponding to a loading rate of 38.4 kg-VS/m(3)/d or 64.4 kg-CODCr/m(3)/d. The short HRT and low pH applied here were enough to separate hydrogen production from methanogenesis. The mixed slurry with a high concentration of organic acids was then converted into CH4 by the mesophilic methane production reactor at a short HRT of 5.0 days, corresponding to a loading rate of 6.6 kg-VS/m(3)/d or 16.3 kg-CODCr/m(3)/d. The experiment was continued for over 150 days, and a stable performance for the simultaneous hydrogen and methane production was obtained. The yields of hydrogen and methane in this study were 205 ml H-2/g VS added and 464 ml CH4/g VS added, respectively. (c) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:4739 / 4746
页数:8
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