Highly Efficient Fullerene-Free Polymer Solar Cells Fabricated with Polythiophene Derivative

被引:322
作者
Qin, Yunpeng [1 ,2 ]
Uddin, Mohammad Afsar [3 ]
Chen, Yu [1 ,4 ]
Jang, Bomee [3 ]
Zhao, Kang [1 ]
Zheng, Zhong [1 ]
Yu, Runnan [1 ]
Shin, Tae Joo [5 ]
Woo, Han Young [3 ]
Hou, Jianhui [1 ,2 ]
机构
[1] Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
[2] Univ Sci & Technol Beijing, Sch Chem & Biol Engn, Beijing 100083, Peoples R China
[3] Korea Univ, Coll Sci, Dept Chem, Seoul 136713, South Korea
[4] Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China
[5] UNIST, UNIST Cent Res Facil UCRF, Ulsan 689798, South Korea
基金
美国国家科学基金会; 新加坡国家研究基金会; 中国博士后科学基金;
关键词
PHOTOVOLTAIC PROPERTIES; MORPHOLOGY CONTROL; MOLECULAR DESIGN; PERFORMANCE; ACCEPTOR; RECOMBINATION; COPOLYMERS; NETWORK; DONOR;
D O I
10.1002/adma.201601803
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A highly efficient fullerene-free polymer solar cell (PSC) based on PDCBT, a polythiophene derivative substituted with alkoxycarbonyl, achieves an impressive power conversion effi ciency of 10.16%, which is the best result in PSCs based on polythiophene derivatives to date. In comparison with a poly(3-hexylthiophene): ITIC-based device, the photovoltaic and morphological properties of the PDCBT: ITIC-based device are carefully investigated and interpreted.
引用
收藏
页码:9416 / +
页数:8
相关论文
共 51 条
[21]   Novel electroluminescent conjugated polyelectrolytes based on polyfluorene [J].
Huang, F ;
Wu, HB ;
Wang, D ;
Yang, W ;
Cao, Y .
CHEMISTRY OF MATERIALS, 2004, 16 (04) :708-716
[22]   Factors Limiting Device Efficiency in Organic Photovoltaics [J].
Janssen, Rene A. J. ;
Nelson, Jenny .
ADVANCED MATERIALS, 2013, 25 (13) :1847-1858
[23]   A strong regioregularity effect in self-organizing conjugated polymer films and high-efficiency polythiophene: fullerene solar cells [J].
Kim, Y ;
Cook, S ;
Tuladhar, SM ;
Choulis, SA ;
Nelson, J ;
Durrant, JR ;
Bradley, DDC ;
Giles, M ;
Mcculloch, I ;
Ha, CS ;
Ree, M .
NATURE MATERIALS, 2006, 5 (03) :197-203
[24]   Intensity Dependence of Current-Voltage Characteristics and Recombination in High-Efficiency Solution-Processed Small-Molecule Solar Cells [J].
Kyaw, Aung Ko Ko ;
Wang, Dong Hwan ;
Gupta, Vinay ;
Leong, Wei Lin ;
Ke, Lin ;
Bazan, Guillermo C. ;
Heeger, Alan J. .
ACS NANO, 2013, 7 (05) :4569-4577
[25]   Processing additives for improved efficiency from bulk heterojunction solar cells [J].
Lee, Jae Kwan ;
Ma, Wan Li ;
Brabec, Christoph J. ;
Yuen, Jonathan ;
Moon, Ji Sun ;
Kim, Jin Young ;
Lee, Kwanghee ;
Bazan, Guillermo C. ;
Heeger, Alan J. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (11) :3619-3623
[26]   High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends [J].
Li, G ;
Shrotriya, V ;
Huang, JS ;
Yao, Y ;
Moriarty, T ;
Emery, K ;
Yang, Y .
NATURE MATERIALS, 2005, 4 (11) :864-868
[27]   An Electron Acceptor Challenging Fullerenes for Efficient Polymer Solar Cells [J].
Lin, Yuze ;
Wang, Jiayu ;
Zhang, Zhi-Guo ;
Bai, Huitao ;
Li, Yongfang ;
Zhu, Daoben ;
Zhan, Xiaowei .
ADVANCED MATERIALS, 2015, 27 (07) :1170-1174
[28]   Non-fullerene acceptors for organic photovoltaics: an emerging horizon [J].
Lin, Yuze ;
Zhan, Xiaowei .
MATERIALS HORIZONS, 2014, 1 (05) :470-488
[29]   Aggregation and morphology control enables multiple cases of high-efficiency polymer solar cells [J].
Liu, Yuhang ;
Zhao, Jingbo ;
Li, Zhengke ;
Mu, Cheng ;
Ma, Wei ;
Hu, Huawei ;
Jiang, Kui ;
Lin, Haoran ;
Ade, Harald ;
Yan, He .
NATURE COMMUNICATIONS, 2014, 5
[30]   Corannulene derivatives as non-fullerene acceptors in solution-processed bulk heterojunction solar cells [J].
Lu, Ru-Qiang ;
Zheng, Yu-Qing ;
Zhou, Yi-Nyu ;
Yan, Xiao-Yun ;
Lei, Ting ;
Shi, Ke ;
Zhou, Yan ;
Pei, Jian ;
Zoppi, Laura ;
Baldridge, Kim K. ;
Siegel, Jay S. ;
Cao, Xiao-Yu .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (48) :20515-20519