A new selective free radical synthesis of aromatic aldehydes by aerobic oxidation of tertiary benzylamines catalysed by N-hydroxyimides and Co(II) under mild conditions.: Polar and enthalpic effects

被引:39
作者
Cecchetto, A
Minisci, F
Recupero, F
Fontana, F
Pedulli, GF
机构
[1] Politecn Milan, Dipartimento Chim Mat & Ingn Chim G Natta, I-20131 Milan, Italy
[2] Univ Bergamo, Dipartimento Ingn, I-24044 Milan, Italy
[3] Univ Bologna, Dipartimento Chim Organ A Mangini, I-40127 Bologna, Italy
关键词
D O I
10.1016/S0040-4039(02)00474-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Tertiary benzylamides are easily and selectively converted into aldehydes by molecular oxygen; the reaction is catalysed by N-hydroxyamides and Co(II). (C) 2002 Published by Elsevier Science Ltd.
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页码:3605 / 3607
页数:3
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