Diethylaminotrimethylsilane mediated aldol condensation of naked aldehydes

被引：27

作者：

Hagiwara, H

Ono, H

Komatsubara, N

Hoshi, T

Suzuki, T

Ando, M

机构：

[1] Niigata Univ, Grad Sch Sci & Technol, Niigata 9502181, Japan

[2] Niigata Univ, Fac Engn, Niigata 9502181, Japan

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 36期

关键词：

aldehydes; aldol reactions; enals;

D O I：

10.1016/S0040-4039(99)01326-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Self-aldol condensation of naked aldehydes in the presence of diethylaminotrimethyl-silane with or without solvent provided unsaturated aldehydes. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

收藏

页码：6627 / 6630

页数：4

相关论文

共 17 条

[1]

ALDER K, 1954, LIEBIGS ANN CHEM, V586, P110

[2]

CASNATI G, 1974, TETRAHEDRON LETT, P959

[3]

COSSUJOUVE M, 1973, B SOC CHIM FR, P249

[4] 1,5-DICARBONYL COMPOUNDS - A GENERAL PREPARATION METHOD [J].

DUHAMEL, P ;

HENNEQUIN, L ;

POIRIER, JM ;

TAVEL, G ;

VOTTERO, C .

TETRAHEDRON, 1986, 42 (17) :4777-4786

[5] Direct 1,4-addition of aldehydes to vinylketones [J].

Hagiwara, H ;

Kato, M .

TETRAHEDRON LETTERS, 1996, 37 (29) :5139-5140

[6] New access to methyl formylcyclopropanecarboxylates via diethylaminotrimethylsilane mediated tandem nucleophilic reaction of aldehyde with methyl 2,3-dihalopropanoate [J].

Hagiwara, H ;

Komatsubara, N ;

Hoshi, T ;

Suzuki, T ;

Ando, M .

TETRAHEDRON LETTERS, 1999, 40 (08) :1523-1526

[7] ZUR DISPROPORTIONIERUNG ALIPHATISCHER ALDEHYDE .2. ALPHA,BETA-UNGESATTIGTE ALDEHYDE [J].

HAUSERMANN, M .

HELVETICA CHIMICA ACTA, 1951, 34 (05) :1482-1491

[8]

Ishikawa T, 1999, SYNLETT, P450

[9] STUDIES ON THE CHEMISTRY OF HETEROCYCLICS .12. PREPARATION OF ACETYLENIC DERIVATIVES OF THIOPHENE [J].

KESKIN, H ;

MILLER, RE ;

NORD, FF .

JOURNAL OF ORGANIC CHEMISTRY, 1951, 16 (02) :199-206

[10] NEUE FURYL- UND PHENYLPOLYALKENALE DURCH ALDOLKONDENSATION [J].

LIPP, M ;

DALLACKER, F .

CHEMISCHE BERICHTE-RECUEIL, 1957, 90 (09) :1730-1734