Phosphinine Lipids: A Successful Marriage between Electron-Acceptor and Self-Assembly Features

被引：28

作者：

He, Xiaoming ^{[1
,2
]}

Lin, Jian-Bin ^{[1
,2
]}

Kan, Wang Hay ^{[1
,2
]}

Baumgartner, Thomas ^{[1
,2
]}

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

[2] Univ Calgary, Ctr Adv Solar Mat, Calgary, AB T2N 1N4, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 34期

基金：

加拿大创新基金会; 加拿大自然科学与工程研究理事会;

关键词：

electron acceptors; liquid crystals; phosphorus heterocycles; self-assembly; BICONTINUOUS CUBIC PHASES; TEMPERATURE IONIC LIQUIDS; PI-CONJUGATED MATERIALS; N-ALKYL CHAINS; PHOSPHONIUM SALTS; ROOM-TEMPERATURE; CRYSTALLINE PHASES; STRUCTURE-PROPERTY; SEMICONDUCTORS; DERIVATIVES;

D O I：

10.1002/anie.201303729

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A push in the right direction: An electron-accepting organophosphorus system has been combined with self-assembly features to create a strongly electron-accepting liquid-crystalline material (see picture). The stability and behavior of the self-assembled liquid crystal could be controlled by adjusting weak intermolecular forces, such as hydrogen bonding and π-π interactions. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8990 / 8994

页数：5

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