Fragmentation of carbohydrate anomeric alkoxy radicals. Synthesis of azasugars

被引：31

作者：

Francisco, CG ^{[1
]}

Freire, R ^{[1
]}

Gonzalez, CC ^{[1
]}

Suarez, E ^{[1
]}

机构：

[1] CSIC,INST PROD NAT & AGROBIOL,LA LAGUNA 38206,SPAIN

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 12期

关键词：

D O I：

10.1016/S0957-4166(97)00188-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of conveniently protected 5-amino-5-deoxy pentoses and 6-amino-6-deoxy hexoses with iodosylbenzene and iodine is an efficient method, via beta-fragmentation of the anomeric alkoxy radicals, for the synthesis of azasugars of the tetrose and pentose series, respectively. (C) 1997 Elsevier Science Ltd.

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页码：1971 / 1974

页数：4

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