Novel polymerization of diethyl fumarate and maleate in aqueous media via cyclodextrin-complexes

被引：13

作者：

Choi, S

Frank, W

Ritter, H

机构：

[1] Univ Dusseldorf, Inst Organ Chem & Makromol Chem, Lehrstuhl 2, D-40225 Dusseldorf, Germany

[2] Univ Dusseldorf, Inst Anorgan Chem & Strukt Chem, Lehrstuhl Mat & Strukt Forsch, D-40225 Dusseldorf, Germany

来源：

REACTIVE & FUNCTIONAL POLYMERS | 2006年 / 66卷 / 01期

关键词：

diethyl fumarate; diethyl maleate; cyclodextrin; isomerization; radical polymerization; redox initiators; x-ray crystallography;

D O I：

10.1016/j.reactfunctpolym.2005.07.013

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Radical polymerization of cyclodextrin (CD) complexed diethyl fumarate (1) and diethyl maleate (2) was investigated using redox initiator in aqueous media at room temperature. Control experiments were carried out showing that 2 does not homopolymerize using radical initiator in bulk at 60 degrees C. Complex 2 undergoes homopolymerization with a cis/trans- isomerization ion in the presence of both CD and redox initiator. The obtained polymers have a similar structure and molecular weight as polymer obtained from the corresponding 1-CD complex. Additionally, the X-ray structure of a alpha-cyclodextrin complex of monomer 1 is represented. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：149 / 156

页数：8

共 31 条

[11]

2-G

[12] DILUTE-SOLUTION PROPERTIES OF SEMIFLEXIBLE POLY(SUBSTITUTED METHYLENES) - INTRINSIC-VISCOSITY OF POLY(DIISOPROPYL FUMARATE) IN BENZENE [J].