Using multimodal ligands to influence network topology in silver(I) coordination polymers

被引：97

作者：

Oxtoby, NS ^{[1
]}

Blake, AJ ^{[1
]}

Champness, NR ^{[1
]}

Wilson, C ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA | 2002年 / 99卷 / 08期

关键词：

D O I：

10.1073/pnas.082647399

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

A range of Ag(l) one- and two-dimensional coordination frameworks has been prepared and structurally characterized by using the multimodal ligand 3,6-di-pyrazin-2-yl-(1,2,4,5)-tetrazine, which offers both monodentate and chelating binding sites. it is demonstrated that multimodal ligands can be used to prepare coordination frameworks with novel and unusual topologies and to influence the precise geometrical arrangement of both ligands and metal centers within such supramolecular arrays.

引用

页码：4905 / 4910

页数：6

共 41 条

[1] Synthesis and structural characterisation of cadmium(II) and zinc(II) coordination polymers with an angular dipyridyl bridging ligand:: parallel interpenetration of two-dimensional sheets with 4.82 topology [J].

Barnett, SA ;

Blake, AJ ;

Champness, NR ;

Nicolson, JEB ;

Wilson, C .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (05) :567-573

[2]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[3]

2-Z

[4]

Baum G, 1997, CHEM COMMUN, P2043

[5] Multicomponent self-assembly: Preferential generation of a rectangular [2x3]G grid by mixed-ligand recognition [J].

Baxter, PNW ;

Lehn, JM ;

Kneisel, BO ;

Fenske, D .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (18) :1978-1981

[6] Multi-modal bridging ligands; effects of ligand functionality, anion and crystallisation solvent in silver(I) co-ordination polymers [J].

Blake, AJ ;

Champness, NR ;

Cooke, PA ;

Nicolson, JEB ;

Wilson, C .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (21) :3811-3819

[7]

Blake AJ, 2000, ANGEW CHEM INT EDIT, V39, P2317, DOI 10.1002/1521-3773(20000703)39:13<2317::AID-ANIE2317>3.0.CO

[8]

2-B

[9] Inorganic crystal engineering using self-assembly of tailored building-blocks [J].

Blake, AJ ;

Champness, NR ;

Hubberstey, P ;

Li, WS ;

Withersby, MA ;

Schröder, M .

COORDINATION CHEMISTRY REVIEWS, 1999, 183 :117-138

[10] Topological isomerism in coordination polymers [J].

Blake, AJ ;

Brooks, NR ;

Champness, NR ;

Crew, M ;

Deveson, A ;

Fenske, D ;

Gregory, DH ;

Hanton, LR ;

Hubberstey, P ;

Schröder, M .

CHEMICAL COMMUNICATIONS, 2001, (16) :1432-1433

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