Topological isomerism in coordination polymers

被引:236
作者
Blake, AJ
Brooks, NR
Champness, NR
Crew, M
Deveson, A
Fenske, D
Gregory, DH
Hanton, LR
Hubberstey, P
Schröder, M
机构
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
[2] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany
[3] Univ Otago, Dept Chem, Dunedin, New Zealand
关键词
D O I
10.1039/b103612m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Three coordination polymers formed between CuI and bpds [bpds = bis(4-pyridyl)disulfide] have been prepared and fully characterised illustrating rare examples of solvent dependent topological isomerism in [(CuI)(2)(bpds)](infinity); tetrahedral Cu4I4 cubane junctions are linked to give either necklace or tubular polymers.
引用
收藏
页码:1432 / 1433
页数:2
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