Mixed Caledonian appinite magmas: Implications for lamprophyre fractionation and high Ba-Sr granite genesis

Ach'Uaine Hybrid appinites represent a rare example of lamprophyric magmas that were demonstrably exactly contemporaneous with felsic differentiates, preserved within a suite of minor, hypabyssal intrusions emplaced at the end of the Caledonian orogeny in northern Scotland. Numerous small stocks, bosses and dykes show outcrop-scale relationships characteristic of mingling between lamprophyric and syenitic magmas, and are commonly cut by sharp-sided granite veins. The mafic rocks are characterised by Ni and Cr abundances and MgO sufficiently high to signal derivation from a mantle source within which radiogenic Sr-87/Sr-86 and nonradiogenic Nd-143/Nd-144 ratios require significant time-integrated incompatible element enrichment. This is manifest in high Pa, Sr and light REE abundances and incompatible element ratios in the derived magmas directly comparable with those of high Ba-Sr granitoids and related rocks. Quantitative major element, trace element, radiogenic and stable isotope modelling is consistent with early fractionation of clinopyroxene and biotite, accompanied by minor crustal assimilation, having driven the evolving lamprophyric magma to cogenetic syenite. Subsequent derivation of granite required a major change to feldspar-dominated crystal fractionation with continued, still minor contamination. The elemental and isotopic characteristics of the granitic terminus are so similar to high Ba-Sr granitoids both locally and worldwide, that these too may have had large mantle components and represent significant juvenile additions to the crust.