A review: Hydrogen generation from borohydride hydrolysis reaction

被引：475

作者：

Liu, B. H. ^{[1
]}

Li, Z. P. ^{[1
]}

机构：

[1] Zhejiang Univ, Coll Mat Sci & Chem Engn, Hangzhou 310027, Peoples R China

来源：

JOURNAL OF POWER SOURCES | 2009年 / 187卷 / 02期

关键词：

Sodium borohydride; Hydrogen generation; Catalyst; Kinetics; Hydrolysis; Borate; WALLED CARBON NANOTUBES; FLUORINATED-METAL-HYDRIDES; INSULATED PRESSURE-VESSELS; SODIUM ALUMINUM-HYDRIDE; ALKALINE NABH4 SOLUTION; B-11 NMR MEASUREMENTS; CATALYTIC HYDROLYSIS; FUEL-CELLS; CO-B; ROOM-TEMPERATURE;

D O I：

10.1016/j.jpowsour.2008.11.032

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this review, a convenient hydrogen generation technology based on sodium borohydride and water as hydrogen carriers has been summarized. The recent progresses in the development of the hydrogen generation from sodium borohydride hydrolysis are reviewed. The NaBH4 hydrolysis behavior is discussed in detail. From reported results. it is considered that hydrogen generation from sodium borohydride hydrolysis is a feasible technology to supply hydrogen for the PEMFC. It has been found that the reported results are encouraging although there are some engineering problems that lie ahead. The critical issues of this hydrogen generation technology have been highlighted and discussed. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：527 / 534

页数：8

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