Synthesis and reactivity of areneruthenium pyranone and pyridinone complexes

被引：11

作者：

Capper, G ^{[1
]}

Carter, LC ^{[1
]}

Davies, DL ^{[1
]}

Fawcett, J ^{[1
]}

Russell, DR ^{[1
]}

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,LEICS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 07期

关键词：

D O I：

10.1039/dt9960001399

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes [Ru(mes)Cl(L)] (mes = 1,3,5-trimethylbenzene; HL = a pyranone or a pyridinone)have been synthesised and characterised. Reaction of [Ru(mes)Cl(L)] (HL = 2-ethyl-3-hydroxypyran-4-one) with CO in the presence of AgBF4 gave [Ru(mes)L(CO)][BF4]. This carbonyl complex reacts with nucleophiles to give substitution products [Ru(mes)L(L')][BF4] (L' = H2O or H(2)NCH(2)Ph). One of the initial complexes, [Ru(mes)Cl(L)] (HL = 2-methyl-3-hydroxypyran-4-one) and the carbonyl complex have been characterised by X-ray diffraction.

引用

页码：1399 / 1403

页数：5

共 30 条

[1]

ABBOTT AP, 1994, J CHEM SOC DA, P3709

[2] COMPETITIVE REACTIONS OF COORDINATED CARBON-MONOXIDE AND METHYL ISOCYANIDE WITH AMINES [J].

ANGELICI, RJ ;

CHRISTIA.PA ;

DOMBEK, BD ;

PFEFFER, GA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 67 (02) :287-294

[3] CARBAMOYL AND ALKOXYCARBONYL COMPLEXES OF TRANSITION-METALS [J].

ANGELICI, RJ .

ACCOUNTS OF CHEMICAL RESEARCH, 1972, 5 (10) :335-&

[4] AQUEOUS SOLUBLE ORGANOMETALLIC COMPLEXES [J].

BARTON, M ;

ATWOOD, JD .

JOURNAL OF COORDINATION CHEMISTRY, 1991, 24 (01) :43-67

[5] DIRECTED SYNTHESIS OF PEPTIDES FROM ALPHA-AMINO-ACID ESTERS AT METAL CENTERS [J].

BECK, W ;

KRAMER, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (11) :1467-1469

[6] 3 POLYMORPHIC FORMS OF 2-ETHYL-3-HYDROXY-4-PYRANONE (ETHYL MALTOL) [J].

BROWN, SD ;

BURGESS, J ;

FAWCETT, J ;

PARSONS, SA ;

RUSSELL, DR ;

WALTHAM, E .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 :1335-1338

[7]

BURGESS J, UNPUB

[8]

CAPPER G, UNPUB

[9] OPTICALLY-ACTIVE PSEUDOCTAHEDRAL RHODIUM(III), IRIDIUM(III), AND RUTHENIUM(II) COMPLEXES WITH ALPHA-AMINO ACIDATO LIGANDS - CRYSTAL-STRUCTURES OF RIRSCSN-[(C5ME5)IR(PRO)CL].1/2H2O AND SIRSCSN-[(C5ME5)IR(PRO)CL].1/2H2O (HPRO = L-PROLINE) [J].

CARMONA, D ;

MENDOZA, A ;

LAHOZ, FJ ;

ORO, LA ;

LAMATA, MP ;

JOSE, ES .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 396 (01) :C17-C21

[10] ARENE RUTHENIUM COMPLEXES WITH PICOLINIC-ACID, 1-AMINOETHYLPHOSPHONOUS ACID AND ALPHA-HYDROXYKETONES - X-RAY STRUCTURE OF [(ETA-1,3,5-C6ME3H3)RUCL(NC5H4CO2)] [J].

CARTER, L ;

DAVIES, DL ;

FAWCETT, J ;

RUSSELL, DR .

POLYHEDRON, 1993, 12 (13) :1599-1602

← 1 2 3 →