Luminescent MTN-Type Cluster-Organic Framework with 2.6 nm Cages

被引：249

作者：

Kang, Yao ^{[1
]}

Wang, Fei ^{[1
]}

Zhang, Jian ^{[1
]}

Bu, Xianhui ^{[2
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 43期

基金：

中国国家自然科学基金; 美国国家科学基金会;

关键词：

BUILDING-BLOCKS; CO2; BINDING; ZEOLITE; ADSORPTION; DESIGN; PORES; CHALCOGENIDES; TETRANUCLEAR; PHOSPHOR; ZMOFS;

D O I：

10.1021/ja308801n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

From a basic tetrahedral Cu4I4 cluster, a new MTN-type cluster-organic framework (COZ-1) containing giant 6(4)5(12) and 5(12) cages was successfully constructed. The 6(4)5(12) cage has an inner diameter of 2.6 nm and a large pore volume of 9.2 nm(3); these tetrahedral Cu4I4 clusters with bulky size offer new opportunities for not only the formation of 4-connected zeotype structures but also the integration of porosity and photoluminescent properties from both the cluster and the framework.

引用

页码：17881 / 17884

页数：4

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