Effect of diazoalkane structure on the stereoselectivity of rhodium(II) (S)-N-(arylsulfonyl)prolinate catalyzed cyclopropanations

被引：121

作者：

Davies, HML ^{[1
]}

Bruzinski, PR ^{[1
]}

Fall, MJ ^{[1
]}

机构：

[1] WAKE FOREST UNIV,DEPT CHEM,WINSTON SALEM,NC 27109

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 24期

关键词：

D O I：

10.1016/0040-4039(96)00823-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rhodium(II) (S)-N-(arylsulfonyl)prolinate catalyzed decomposition of diazoalkanes containing a methyl ester and either a vinyl or a phenyl group in the presence of alkenes results in highly diastereoselective and enantioselective cyclopropanations. (C) 1996 Elsevier Science Ltd

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收藏

页码：4133 / 4136

页数：4

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