Experimental evidence from H/D exchange studies for the failure of direct C-C coupling mechanisms in the methanol-to-olefin process catalyzed by HSAPO-34

被引：105

作者：

Marcus, DM ^{[1
]}

McLachlan, KA ^{[1
]}

Wildman, MA ^{[1
]}

Ehresmann, JO ^{[1
]}

Kletnieks, PW ^{[1
]}

Haw, JF ^{[1
]}

机构：

[1] Univ So Calif, Dept Chem, Los Angeles, CA 90089 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 19期

关键词：

heterogeneous catalysis; isotopic labeling; methanol-to-olefin process; zeolites;

D O I：

10.1002/anie.200504372

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Pool view preferred: In agreement with recent theoretical work, a new line of experimental evidence was obtained in support of the controversial claim that direct mechanisms do not couple methanol to ethylene in the catalyzed methanol-to-olefin process. The results preclude carbene routes and oxonium ylide mechanisms, among others (see picture), in favor of the hydrocarbon pool mechanism. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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收藏

页码：3133 / 3136

页数：4

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