In situ photoelectron spectroscopy at the liquid/nanoparticle interface

被引:48
作者
Brown, Matthew A. [1 ]
Jordan, Inga [2 ]
Redondo, Amaia Beloqui [1 ]
Kleibert, Armin [3 ]
Woerner, Hans Jakob [2 ]
van Bokhoven, Jeroen A. [1 ,3 ]
机构
[1] ETH, Inst Chem & Bioengn, CH-8093 Zurich, Switzerland
[2] ETH, Phys Chem Lab, CH-8093 Zurich, Switzerland
[3] Paul Scherrer Inst, CH-5232 Villigen, Switzerland
关键词
Liquid microjet; In situ X-ray photoelectron spectroscopy; Time-resolved photoelectron spectroscopy; Liquid/solid interface; Nanoparticles; Colloidal suspension; LIQUID-VAPOR INTERFACE; ELECTRONIC-STRUCTURE; NANOPARTICLES; CHEMISTRY; WATER; GOLD; ACID; PHOTOEMISSION; STATE; SOLAR;
D O I
10.1016/j.susc.2013.01.012
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this prospective, an overview of in situ photoelectron spectroscopy at the liquid/nanoparticle (NP) interface is presented. Recently it was shown that by using a liquid microjet in combination with synchrotron radiation electronic structure measurements at the aqueous solution/nanoparticle interface can be realized. We discuss unique aspects of this experiment including the liquid microjet source while outlining potential applications and opportunities. A special section is devoted to laboratory based in situ ultrafast pump-probe photoelectron spectroscopy at the liquid/nanopartide interface. In situ photoelectron spectroscopy at the liquid/nanoparticle interface has potential to benefit researchers across several disciplines including chemistry, physics, biology, materials science and nanomedicine. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 6
页数:6
相关论文
共 47 条
[1]   Size-dependent surface charging of nanoparticles [J].
Abbas, Zareen ;
Labbez, Christophe ;
Nordholm, Sture ;
Ahlberg, Elisabet .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (15) :5715-5723
[2]  
[Anonymous], J PHYS D
[3]   INTERACTION OF LOW-ENERGY ELECTRONS WITH SILICON DIOXIDE [J].
ASHLEY, JC ;
ANDERSON, VE .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1981, 24 (02) :127-148
[4]   Jahn-Teller distortion in the phosphorescent excited state of three-coordinate Au(I) phosphine complexes [J].
Barakat, KA ;
Cundari, TR ;
Omary, MA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (47) :14228-14229
[5]   Ion spatial distributions at the liquid-vapor interface of aqueous potassium fluoride solutions [J].
Brown, Matthew A. ;
D'Auria, Raffaella ;
Kuo, I. -F. William ;
Krisch, Maria J. ;
Starr, David E. ;
Bluhm, Hendrik ;
Tobias, Douglas J. ;
Hemminger, John C. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (32) :4778-4784
[6]   Electronic Structures of Formic Acid (HCOOH) and Formate (HCOO-) in Aqueous Solutions [J].
Brown, Matthew A. ;
Vila, Fernando ;
Sterrer, Martin ;
Thuermer, Stephan ;
Winter, Bernd ;
Ammann, Markus ;
Rehr, John J. ;
van Bokhoven, Jeroen A. .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2012, 3 (13) :1754-1759
[7]   Changes in the Silanol Protonation State Measured In Situ at the Silica-Aqueous Interface [J].
Brown, Matthew A. ;
Huthwelker, Thomas ;
Redondo, Amaia Beloqui ;
Janousch, Markus ;
Faubel, Manfred ;
Arrell, Christopher A. ;
Scarongella, Mariateresa ;
Chergui, Majed ;
van Bokhoven, Jeroen A. .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2012, 3 (02) :231-235
[8]   Oxidation of Au by Surface OH: Nucleation and Electronic Structure of Gold on Hydroxylated MgO(001) [J].
Brown, Matthew A. ;
Fujimori, Yuichi ;
Ringleb, Franziska ;
Shao, Xiang ;
Stavale, Fernando ;
Nilius, Niklas ;
Sterrer, Martin ;
Freund, Hans-Joachim .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (27) :10668-10676
[9]   Electronic structure of sub-10 nm colloidal silica nanoparticles measured by in situ photoelectron spectroscopy at the aqueous-solid interface [J].
Brown, Matthew A. ;
Seidel, Robert ;
Thuermer, Stephan ;
Faubel, Manfred ;
Hemminger, John C. ;
van Bokhoven, Jeroen A. ;
Winter, Bernd ;
Sterrer, Martin .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (28) :12720-12723
[10]   Initial Formation of Positively Charged Gold on MgO(001) Thin Films: Identification by Experiment and Structural Assignment by Theory [J].
Brown, Matthew A. ;
Ringleb, Franziska ;
Fujimori, Yuichi ;
Sterrer, Martin ;
Freund, Hans-Joachim ;
Preda, Gloria ;
Pacchioni, Gianfranco .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (20) :10114-10124