Phosphabarrelene-rhodium complexes as highly active catalysts for isomerization free hydroformylation of internal alkenes

被引：67

作者：

Breit, B ^{[1
]}

Fuchs, E ^{[1
]}

机构：

[1] Univ Freiburg, Inst Organ Chem & Biochem, D-79104 Freiburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 06期

关键词：

D O I：

10.1039/b315709a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new class of phosphabarrelene-rhodium catalysts is described which allows for the first time hydroformylation of internal alkenes with very high activity and which proceeds essentially free of alkene isomerization.

引用

页码：694 / 695

页数：2

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