Fullerenes in the analytical sciences

被引:75
作者
Baena, JR [1 ]
Gallego, M [1 ]
Valcárcel, M [1 ]
机构
[1] Univ Cordoba, Div Analyt Chem, E-14071 Cordoba, Spain
关键词
fullerenes; separation and determination; chemical sensors; sorbent materials;
D O I
10.1016/S0165-9936(02)00306-0
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
An overview is presented of the impact of fullerenes in analytical chemistry and of their general applications. Fullerenes can be target analytes and methods for their separation, identification and quantification are systematically considered. Fullerenes are also used as chromatographic stationary phases, as materials for building both electrochemical and optical sensors, and as sorbent materials for automatic on-line clean up and preconcentration. These applications and the analytical prospects for fullerenes are discussed. (C) 2002 Published by Elsevier Science B.V. All rights reserved.
引用
收藏
页码:187 / 198
页数:12
相关论文
共 52 条
[1]  
ABRAHAM MH, 1993, CHEM COMMUN, P1863
[2]   A novel optical oxygen sensing system based on triplet-triplet reflectance of fullerene C60-polystyrene film by time-resolved spectroscopy using diffuse reflectance laser flash photolysis [J].
Amao, Y ;
Asai, K ;
Okura, I .
ANALYST, 2000, 125 (03) :523-526
[3]   Speciation of inorganic lead and trialkyllead compounds by flame atomic absorption spectrometry following continuous selective preconcentration from aqueous solutions [J].
Baena, JR ;
Gallego, M ;
Valcárcel, M .
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1999, 54 (13) :1869-1879
[4]   Speciation of inorganic lead and ionic alkyllead compounds by GC/MS in prescreened rainwaters [J].
Baena, JR ;
Cárdenas, S ;
Gallego, M ;
Valcárcel, M .
ANALYTICAL CHEMISTRY, 2000, 72 (07) :1510-1517
[5]   Comparison of three coupled gas chromatographic detectors (MS, MIP-AES, ICP-TOFMS) for organolead speciation analysis [J].
Baena, JR ;
Gallego, M ;
Valcárcel, M ;
Leenaers, J ;
Adams, FC .
ANALYTICAL CHEMISTRY, 2001, 73 (16) :3927-3934
[6]   Group speciation of metal dithiocarbamates by sorption on C60 fullerene [J].
Baena, JR ;
Gallego, M ;
Valcárcel, M .
ANALYST, 2000, 125 (08) :1495-1499
[7]  
BAENA JR, 2000, LC GC EUR, V13, P830
[8]   Analytical potential of fullerene as adsorbent for organic and organometallic compounds from aqueous solutions [J].
Ballesteros, E ;
Gallego, M ;
Valcárcel, M .
JOURNAL OF CHROMATOGRAPHY A, 2000, 869 (1-2) :101-110
[9]  
Bisaglia M, 2000, J NEUROCHEM, V74, P1197
[10]   Antimycobacterial activity of ionic fullerene derivatives [J].
Bosi, S ;
Da Ros, T ;
Castellano, S ;
Banfi, E ;
Prato, M .
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2000, 10 (10) :1043-1045