Graphene oxide nanoplatelets composite membrane with hydrophilic and antifouling properties for wastewater treatment

被引:493
作者
Lee, Jaewoo [1 ]
Chae, Hee-Ro [1 ]
Won, Young June [1 ]
Lee, Kibaek [1 ]
Lee, Chung-Hak [1 ]
Lee, Hong H. [1 ,4 ]
Kim, In-Chul [2 ]
Lee, Jong-min [3 ]
机构
[1] Seoul Natl Univ, Sch Chem & Biol Engn, Seoul 151744, South Korea
[2] Korea Res Inst Chem Technol, Res Ctr Biobased Chem, Taejon 305600, South Korea
[3] Woongjin Chem Co Ltd, Gumi 730030, Kyungbuk, South Korea
[4] Soulbrain Co Ltd, R&D Ctr, Yongin 446599, Geonggi Do, South Korea
基金
新加坡国家研究基金会;
关键词
Graphene oxide; Polysulfone membrane; Hydrophilicity; Anti-biolouling; Membrane bioreactor; ULTRAFILTRATION MEMBRANES; SURFACE MODIFICATION; RAMAN-SPECTROSCOPY; BIOREACTORS; MICROFILTRATION; FABRICATION; TECHNOLOGY; SLUDGE; FILMS; EPS;
D O I
10.1016/j.memsci.2013.08.017
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
As a potential remedy for the water shortage, membrane bioreactor (MBR) has emerged and attracted much attention in the held of wastewater treatment and reuse. However, MBRs have membrane fouling which is the major obstacle in maximizing their efficiency leading to short membrane lifetime and high operating costs. Here we demonstrate that the nanoplatelets of graphene oxide included in the preparation of membrane suppress the fouling to such an extent that a fivefold lengthening is achieved of the time between chemical cleanings. It was quite a surprise to discover that inclusion of only about 1 wt% of graphene oxide in the fabrication of membrane could spring up a new generation of membrane with anti-fouling capability for MBRs. Utilization of graphene oxide introduced here for wastewater treatment would open and facilitate graphene-based environmental applications., (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:223 / 230
页数:8
相关论文
共 45 条
[1]   Toxicity of a polymer-graphene oxide composite against bacterial planktonic cells, biofilms, and mammalian cells [J].
Carpio, Isis E. Mejias ;
Santos, Catherine M. ;
Wei, Xin ;
Rodrigues, Debora F. .
NANOSCALE, 2012, 4 (15) :4746-4756
[2]   Carbon nanotube blended polyethersulfone membranes for fouling control in water treatment [J].
Celik, Evrim ;
Park, Hosik ;
Choi, Hyeongyu ;
Choi, Heechul .
WATER RESEARCH, 2011, 45 (01) :274-282
[3]   Membrane fouling in membrane bioreactors for wastewater treatment [J].
Chang, IS ;
Le Clech, P ;
Jefferson, B ;
Judd, S .
JOURNAL OF ENVIRONMENTAL ENGINEERING, 2002, 128 (11) :1018-1029
[4]  
Cheryan M., 1998, Ultrafiltration and Microfiltration Handbook
[5]   Fabrication and characterization of multi-walled carbon nanotubes/polymer blend membranes [J].
Choi, Jae-Hyun ;
Jegal, Jonggeon ;
Kim, Woo-Nyon .
JOURNAL OF MEMBRANE SCIENCE, 2006, 284 (1-2) :406-415
[6]   Preparation and characterization of graphene oxide paper [J].
Dikin, Dmitriy A. ;
Stankovich, Sasha ;
Zimney, Eric J. ;
Piner, Richard D. ;
Dommett, Geoffrey H. B. ;
Evmenenko, Guennadi ;
Nguyen, SonBinh T. ;
Ruoff, Rodney S. .
NATURE, 2007, 448 (7152) :457-460
[7]   Membrane fouling - a review on the role of EPS [J].
Drews, Anja ;
Lee, Chung-Hak ;
Kraume, Matthias .
DESALINATION, 2006, 200 (1-3) :186-188
[8]   The chemistry of graphene oxide [J].
Dreyer, Daniel R. ;
Park, Sungjin ;
Bielawski, Christopher W. ;
Ruoff, Rodney S. .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :228-240
[9]   Electronic transport properties of individual chemically reduced graphene oxide sheets [J].
Gomez-Navarro, Cristina ;
Weitz, R. Thomas ;
Bittner, Alexander M. ;
Scolari, Matteo ;
Mews, Alf ;
Burghard, Marko ;
Kern, Klaus .
NANO LETTERS, 2007, 7 (11) :3499-3503
[10]   Spatially resolved raman spectroscopy of single- and few-layer graphene [J].
Graf, D. ;
Molitor, F. ;
Ensslin, K. ;
Stampfer, C. ;
Jungen, A. ;
Hierold, C. ;
Wirtz, L. .
NANO LETTERS, 2007, 7 (02) :238-242