Hydrothermal chemistry of the copper-triazolate system:: A microporous metal-organic framework constructed from magnetic {Cu3(μ3-OH)(triazolate)3}2+ building blocks, and related materials

被引：148

作者：

Ouellette, Wayne

Yu, Ming Hui

O'Connor, Charles J.

Hagrman, Douglas

Zubieta, Jon ^{[1
]}

机构：

[1] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA

[2] Univ New Orleans, Adv Mat Res Inst, New Orleans, LA 70148 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 21期

关键词：

copper; hydrothermal synthesis; magnetic properties; microporous materials; N ligands;

D O I：

10.1002/anie.200504128

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Networking with triazolate: Three new compounds containing networks of CuI or CuII ions linked by 1,2,4-triazolate (trz) ligands were prepared by hydrothermal synthesis. The microporous metal-organic framework {Cu3(μ3-OH)-(trz) 3(OH)2(H2O)4}n, which is built up from magnetic triangles, forms 17 x 13 x 13 Å3 cavities (see picture; Cu dark blue, O red, N light blue, C black). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：3497 / 3500

页数：4

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