Organic-inorganic composite oxide phases:: one-dimensional molybdenum oxide chains entrained within a three-dimensional coordination complex cationic framework in [{Cu2(triazolate)2(H2O)2}Mo4O13]

被引:128
作者
Hagrman, D [1 ]
Zubieta, J [1 ]
机构
[1] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA
关键词
D O I
10.1039/a804689a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The hydrothermal reaction of MoO3, CuSO4. 5H(2)O, 1,2,4-triazole and H2O produces a 50% yield of [{Cu-2-(triazolate)(2)(H2O)(2)}Mo4O13], a material constructed from {Mo4O13}(n)(2n-) chains entrained within the three dimensional framework provided by the {Cu-2(triazolate)(2)(H2O)(2)}(n)(2n+) polymeric complex.
引用
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页码:2005 / 2006
页数:2
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