A Bistable Porous Coordination Polymer with a Bond-Switching Mechanism Showing Reversible Structural and Functional Transformations

被引：177

作者：

Ghosh, Sujit K. ^{[3
]}

Kaneko, Wakako ^{[3
]}

Kiriya, Daisuke ^{[3
]}

Ohba, Masaaki ^{[3
]}

Kitagawa, Susumu ^{[1
,2
,3
]}

机构：

[1] JST, ERATO, Kitagawa Integrated Pore Project, Shimogyo Ku, Kyoto 6008815, Japan

[2] Kyoto Univ, Inst Integrated Cell Mat Sci iCeMS, Sokyo Ku, Kyoto 6068501, Japan

[3] Kyoto Univ, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 46期

关键词：

absorption; bistable frameworks; coordination polymers; magnetic properties; molecular dynamics;

D O I：

10.1002/anie.200802803

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ring the changes: A 2D crystalline coordination polymer 1 is transformed reversibly into a 3D crystal 1a by dehydration. This reversible structural transformation is accompanied by a change in optical and magnetic properties. The 3D coordination framework absorbs H2O molecules but rejects common organic solvents, such as MeOH, EtOH, THF, and Me2CO. (Figure Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8843 / 8847

页数：5

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