The first organically templated beryllium phosphite [NH3(CH2)3NH3]•Be3 (HPO3)4:: Hydrothermal synthesis and X-ray crystal structure

被引：51

作者：

Fu, WS ^{[1
]}

Wang, L ^{[1
]}

Shi, Z ^{[1
]}

Li, GH ^{[1
]}

Chen, XB ^{[1
]}

Dai, ZM ^{[1
]}

Yang, L ^{[1
]}

Feng, SH ^{[1
]}

机构：

[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2004年 / 4卷 / 02期

关键词：

D O I：

10.1021/cg034116t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An organically templated beryllophosphite, [H3N(CH2)(3)NH3](.)[Be-3(HPO3)(4)] 1, has been synthesized under mild hydrothermal conditions and characterized by single-crystal X-ray diffraction. It is the first beryllophosphite using organic amine as a structure-direction agent. Compound 1 crystallizes in a monoclinic system, space group P2(1)/c with cell parameters: a = 8.5983(15) Angstrom, b = 13.1561(19) Angstrom, c = 13.460(2) Angstrom, beta = 92.470(5)degrees, and Z = 4. The three-dimensional framework is built up from strictly alternating BeO4 tetrahedra and [HPO32-] pseudopyramid by sharing vertices. A new type of network containing 4-, 6-, 8-, 10-, 12-membered rings makes up the inorganic framework. The 1,3-diammonium propane template molecules are located in 8-membered ring windows. The compound was characterized by IR spectroscopy, inductively coupled plasma (ICP), and differential thermal and thermogravimetric analyses.

引用

页码：297 / 300

页数：4

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