Homoleptic alkaline earth metal bis(trifluoromethanesulfonyl)imide complex compounds obtained from an ionic liquid

被引：59

作者：

Babai, A ^{[1
]}

Mudring, AV ^{[1
]}

机构：

[1] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 08期

关键词：

D O I：

10.1021/ic051820l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first homoleptic alkaline earth bis(trifluoromethanesulfonyl)imide (Tf2N) complexes [mppyr](2)[Ca(Tt(2)N)(4)], [mppyr](2)-[Sr(Tf2N)(4)], and [mppyr][Ba(Tf2N)(3)] were crystallized from a solution of the respective alkaline earth bis(trifluoromethanesulfonyl)imide and the ionic liquid [mppyr][Tf2N] (mppyr = 1,1-N-methyl-N-propylpyrrolidinium). In the calcium and strontium compounds, the alkaline earth metal (AE) is coordinated by four bidentately chelating Tf2N ligands to form isolated (distorted) square antiprismatic [AE(Tf2N)(4)](2-) complexes which are separated by N-methyl-N-propylpyrrolidinium cations. In contrast, the barium compound, [mppyr][Ba(Tf2N)(3)], forms an extended structure. Here the alkaline earth cation is surrounded by six oxygen atoms belonging to three Tf2N- anions which coordinate in a bidentate chelating fashion, Three further oxygen atoms of the same ligands are linking the Ba2+ cations to infinite (1)(infinity)[Ba(Tf2N)(3)] chains.

引用

页码：3249 / 3255

页数：7

共 45 条

[1]

[Anonymous], ANGEW CHEM

[2] Anhydrous praseodymium salts in the ionic liquid [bmpyr][Tf2N]:: Structural and optical properties of [bmpyr]4[PrI6][Tf2N] and [bmyr]2[Pr(Tf2N)5] [J].

Babai, A ;

Mudring, AV .

CHEMISTRY OF MATERIALS, 2005, 17 (25) :6230-6238

[3]

BABAI A, IN PRESS J CHEM SOC

[4] Structural characterization of a lanthanum bistriflimide complex, La(N(SO2CF3)2)3(H2O)3, and an investigation of La, Sm, and Eu electrochemistry in a room-temperature ionic liquid, [Me3NnBu][N(SO2CF3)2] [J].

Bhatt, AI ;

May, I ;

Volkovich, VA ;

Collison, D ;

Helliwell, M ;

Polovov, IB ;

Lewin, RG .

INORGANIC CHEMISTRY, 2005, 44 (14) :4934-4940

[5] Group 15 quaternary alkyl bistrflimides: ionic liquids with potential application in electropositive metal deposition and as supporting electrolytes [J].

Bhatt, AI ;

May, I ;

Volkovich, VA ;

Hetherington, ME ;

Lewin, B ;

Thied, RC ;

Ertok, N .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (24) :4532-4534

[6]

BRAZEL CS, 2005, IONIC LIQUDS POLYM S

[7] Raman investigation of the ionic liquid N-methyl-N-propylpyrrolidinium bis(trifluoromethanesulfonyl)imide and its mixture with LiN(SO2CF3)2 [J].

Castriota, M ;

Caruso, T ;

Agostino, RG ;

Cazzanelli, E ;

Henderson, WA ;

Passerini, S .

JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (01) :92-96

[8] Electrodeposition of cesium at mercury electrodes in the tri-1-butylmethylammonium bis((trifluoromethyl)sulfonyl)imide room-temperature ionic liquid [J].

Chen, PY ;

Hussey, CL .

ELECTROCHIMICA ACTA, 2004, 49 (28) :5125-5138

[9]

*CRYST IMP GBR, 1996, DIAM VERS 2 1E

[10] Structural diversity in Lewis-base complexes of lithium triflamide [J].

Davidson, MG ;

Raithby, PR ;

Johnson, AL ;

Bolton, PD .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (18) :3445-3452

← 1 2 3 4 5 →