P2-type layered Na0.45Ni0.22Co0.11Mn0.66O2 as intercalation host material for lithium and sodium batteries

被引：90

作者：

Buchholz, Daniel ^{[1
]}

Chagas, Luciana Gomes ^{[1
]}

Winter, Martin ^{[1
]}

Passerini, Stefano ^{[1
]}

机构：

[1] Univ Munster, Inst Phys Chem, MEET Battery Res Ctr, D-48149 Munster, Germany

来源：

ELECTROCHIMICA ACTA | 2013年 / 110卷

关键词：

Cathode material; Layered; High stability; Sodium and lithium batteries; Intercalation; NA-ION BATTERIES; CATHODE MATERIAL; ENERGY-STORAGE; ELECTRODES; T2; NI; O2;

D O I：

10.1016/j.electacta.2013.02.109

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

070208 [无线电物理];

摘要：

Herein is reported the electrochemical performance of Na0.45Ni0.22Co0.11Mn0.66O2 as cathode material for lithium and sodium batteries. The material is able to reversibly accommodate both cation species but reveals a much better electrochemical performance towards Na-ion intercalation. Upon galvanostatic cycling for 100 cycles a much higher capacity retention (82% vs. Na, 61% vs. Li) and higher coulombic efficiency (99.5% vs. Na, 98.5% vs. Li) are shown by the sodium-based system. The worse electrochemical performance of the lithium-based system can be explained by the much higher irreversibility of the Mn3+/Mn4+ redox process. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：208 / 213

页数：6

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